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So, the Michael reaction is a particular type of conjugate addition reaction that ɑ, β -unsaturated carbonyl compounds undergo with nucleophiles. In general, ɑ, β-unsaturated carbonyl compounds can undergo a 1,2- or 1,4-addition reaction. 1,2-addtion reactions are all of those where the nucleophile attacks the carbonyl group.

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Michael Addition •The Michael reaction is a useful method for. forming carbon-carbon bonds. •Gives 1,5 dioxo derivatives! •It is also useful in that the product of the . reaction can undergo an intramolecular. aldol condensation to form a six-membered . ring. One such application is called the Robinson. annulation.

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Conjugate addition of carbon nucleophiles to α,β-unsaturated carbonyl compounds via organocuprates is an essential C-C bond forming process in synthetic organic chemistry. 1,2 Substantial progress is being made also on the use of organocopper in new environmentally

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Oct 22, 2020 · The reaction as originally reported involved formation of a silyl enol ether followed by treatment with palladium(II) acetate and benzoquinone to yield the corresponding enone. The original publication noted its utility for regeneration of unsaturation following 1,4-addition with nucleophiles such as organocuprates.

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Abstract. The copper-catalyzed enantioselective conjugate addition (ECA) of organometallic nucleophiles to electron-deficient alkenes (Michael acceptors) represents an efficient and attractive methodology for providing a wide range of relevant chiral molecules. In order to increase the attractiveness of this useful catalytic transformation, some Michael acceptors bearing challenging electron-deficient functions (i.e., aldehydes, thioesters, acylimidazoles, N -acyloxazolidinones, N ...

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These nucleophiles serve as acyl anion equivalents in Lewis base catalysed aldol addition reactions and allow for the preparation of cross-benzoin and glycolate-aldol products in high yield and ...

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